ID   1.14.13.85
DE   Glyceollin synthase.
AN   Dimethylallyl-3,6a,9-trihydroxypterocarpan cyclase.
CA   2-(or 4-)dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + NADPH +
CA   O(2) = glyceollin + NADP(+) + 2 H(2)O.
CF   Heme-thiolate.
CC   -!- Glyceollins II and III are formed from 2-dimethylallyl-
CC       (6aS,11aS)-3,6a,9-trihydroxypterocarpan whereas glyceollin I is
CC       formed from the 4-isomer.
PR   PROSITE; PDOC00081;
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